Reaction Pathways in Crystalline Host-Guest Inclusion Complexes: Rotation by a Net 180 deg of the Acetyl Group on Photoaddition of Guest-Acetophenone and m-Chloroacetophenone to the Atom C5 of Host Deoxycholic acid

DOI: 10.1021/ja00299a048

Source and publish data:

Journal of the American Chemical Society p. 4058 - 4070 (1985)

Update date:2022-07-31

Topics:

Authors:

Tang, C. P.

Chang, H. C.

Popovitz-Biro, R.

Frolow, F.

Lahav, M.

et al. et al.

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Article abstract of DOI:10.1021/ja00299a048

The crystalline host-guest channel inclusion complexes 5:2 (DCA) deoxycholic acid-acetophenone (C6H5C'OCH3) and 3:1 DCA-m-chloroacetophenone (ClC6H4C'OCH3) each yield on UV irradiation a photoproduct via addition of guest to the steroid tertiary carbon at

Full text of DOI:10.1021/ja00299a048

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