TRANSPOSITION OF ALLYLIC ALCOHOLS CONTROLLED BY THE Ph2PO GROUP: REAGENTS FOR α-HYDROXY-DIENE SYNTHESIS BY THE HORNER-WITTIG REACTION

DOI: 10.1016/S0040-4039(00)61892-0

Source and publish data:

Tetrahedron Letters p. 249 - 252 (1985)

Update date:2022-07-29

Topics:

Authors:

Brown, Paul S.

McElroy, Andrew B.

Warren Stuart

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Article abstract of DOI:10.1016/S0040-4039(00)61892-0

4-Hydroxy-2-alkenyldiphenylphosphine oxides, prepared by a phosphorus-controlled allylic rearrangement, give dianions and hence α-hydroxydienes (substitued penta-2,4-dienols) by the Horner-Wittig reaction.

Full text of DOI:10.1016/S0040-4039(00)61892-0

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