TRANSPOSITION OF ALLYLIC ALCOHOLS CONTROLLED BY THE Ph2PO GROUP: REAGENTS FOR α-HYDROXY-DIENE SYNTHESIS BY THE HORNER-WITTIG REACTION

DOI: 10.1016/S0040-4039(00)61892-0

Source and publish data:

Tetrahedron Letters p. 249 - 252 (1985)

Update date:2022-07-29

Topics:

Authors:

Brown, Paul S.

McElroy, Andrew B.

Warren Stuart

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)61892-0

4-Hydroxy-2-alkenyldiphenylphosphine oxides, prepared by a phosphorus-controlled allylic rearrangement, give dianions and hence α-hydroxydienes (substitued penta-2,4-dienols) by the Horner-Wittig reaction.

Full text of DOI:10.1016/S0040-4039(00)61892-0

Products guided by the article

Product name:3-Buten-2-ol, 1-(diphenylphosphinyl)-2-methyl-

Cas No:96322-91-7

R&D Labs maybe for 96322-91-7

Shanghai Hanhong Scientific Co.,Ltd.

website:http://www.chemvia.com

Contact:+86-21-64541543,54280654,13918533501

Address:Jiachuan Road 245
waho int'l company

Contact:+86-579-85206992

Address:No 451 chouzhou north road ,room 1106 int'l business center , yiwu ,china
Jinan Jiaquan Chemical Co.,Ltd

Contact:+86-531-62318366

Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
ZHUHAI HAIRUIDE BIOSCIENCE AND TECHNOLOGY CO.,LTD

website:http://www.zhhairuide.com

Contact:+8613326687259/+86-756-7789199

Address:No.10 Yonghui Road

Relevant to this article

Proton-Ionizable Crown Compounds. 1. Synthesis, Complexation Propertie , and Structural Studies of Macrocyclic Polyether-Diester Ligands Containing a Triazole Subcyclic Unit

Doi:10.1021/jo00217a010
(1985)
3-Bromo-2-(tert-butylsulfonyl)-1-propene. A multi-coupling reagent Part 1.

Doi:10.1016/S0040-4039(00)61901-9
(1985)
DILITHIATED SYNTHONS OF TERTIARY BENZAMIDES, PHTHALAMIDES, AND O,O'-ARYL DICARBAMATES

Doi:10.1016/S0040-4039(00)98418-1
(1985)
Analysis of Configuration and Conformation of Furanose Ring in Carbohydrate and Nucleoside by Vibrational Circular Dichroism

Doi:10.1021/acs.orglett.6b03626
(2017)
TOTAL SYNTHESIS OF (+)-(1,2,3/4,5)-2,3,4,5-TETRAHYDROXYCYCLOHEXANE-1-METHANOL AND (+)-(1,3/2,4,5)-5-AMINO-2,3,4-TRIHYDROXYCYCLOHEXANE-1-METHANOL <(+)-VALIDAMINE>. X-RAY CRYSTAL STRUCTURE OF (3s)-(+)-2-EXO-BROMO-4,8-DIOXATRICYCLO<4.2.1.0^3,7>NONA

Doi:10.1039/P19850000903
(1985)
3-Bromo-2-(tert-butylsulfonyl)-1-propene. A multi-coupling reagent. Part 2.

Doi:10.1016/S0040-4039(00)95089-5
(1985)

Article Doi