Journal of Fluorine Chemistry p. 37 - 39 (1998)
Update date:2022-09-26
Topics:
Shellhamer, Dale F.
Jones, Brian C.
Pettus, Benjamin J.
Pettus, Tobiah L.
Stringer, Joy Merry
Heasley, Victor L.
Reaction of xenon difluoride (XeF2) and iodine (I2) or N-iodosuccinimide (NIS) with alkenes gives iodofluoro products in good yields. Aromatics react with XeF2 and I2 or NIS to undergo electrophilic aromatic iodination. Iodine monofluoride (IF) generated from XeF2 is less reactive than IF generated from I2 and fluorine gas. This difference in reactivity suggests that the interhalogen IF is delivered to the alkene or aromatic from a complex with XeF2.
View MoreContact:+33-5-34012600
Address:28 ZA des Pignès
Contact:+49-9398-993127
Address:Untertorstr. 27
Guangzhou Swan Chemical Co., Ltd.
Contact:+86-20-31075659
Address:NO.301, Hong ba fang investment BLDG 1,Guan chong village,Shiqi town,Panyu district,Guangzhou
Zhengzhou Gecko Scientific Inc.
Contact:0371-88884176
Address:56 Hongzhuan Road, Zhengzhou, China
Changzhou Sunlight Pharmaceutical Co., Ltd.
Contact:+86-519-83131668;83139028;83138042;83137041
Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
Doi:10.1016/S0022-328X(00)92259-9
(1977)Doi:10.1021/jo00871a012
(1976)Doi:10.1016/S0040-4039(01)92281-6
(1974)Doi:10.1248/cpb.23.3101
(1975)Doi:10.1021/jm00226a007
(1976)Doi:10.1021/jm00226a010
(1976)
