Journal of Fluorine Chemistry p. 37 - 39 (1998)
Update date:2022-09-26
Topics:
Shellhamer, Dale F.
Jones, Brian C.
Pettus, Benjamin J.
Pettus, Tobiah L.
Stringer, Joy Merry
Heasley, Victor L.
Reaction of xenon difluoride (XeF2) and iodine (I2) or N-iodosuccinimide (NIS) with alkenes gives iodofluoro products in good yields. Aromatics react with XeF2 and I2 or NIS to undergo electrophilic aromatic iodination. Iodine monofluoride (IF) generated from XeF2 is less reactive than IF generated from I2 and fluorine gas. This difference in reactivity suggests that the interhalogen IF is delivered to the alkene or aromatic from a complex with XeF2.
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