Journal of Organic Chemistry p. 3086 - 3091 (1985)
Update date:2022-08-03
Topics:
Schultz, Arthur G.
Lavieri, Frank P.
Snead, Thomas E.
The preparation and intramolecular Diels-Alder reactions of a series of 6-alkenyl-6-(methoxycarbonyl)2,4-cyclohexadien-1-ones are described.The resulting tricyclic β,γ-enones undergo the oxa-di-?-methane rearrangement to give substrates of potential use in the construction of polyquinane natural products.This methodology provides a means for construction of tetracyclic rings of type A by C-alkylation of the synthetic equivalence of enolate B.
View MoreLishui Nanming Chemical Co., Ltd(expird)
Contact:+86-0578-2134101，2697830
Address:No.19 Tongji Road Shuige Industrial zone
Jining tiansheng chemical co.,ltd.
Contact:+86-537-5158722
Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
website:https://www.sinoshiny.com/products
Contact:+86-20-62802632;62802633
Address:Room 330 GIGCAS Building,No.511 Kehua Street,Tianhe District
Tianjin Anda North Industrial & Business Co.Ltd.
Contact:86-22-24999306
Address:No.11 Erwei Road,Dongli Development Area,Tianjin,China
Hangzhou Yanshan Chemical Co.,Ltd.
Contact:86-571- 87698076
Address:Room 1001, #1 Building, Zhongtian MCC, No.2 Youzhinong, Wenyi West Road, Xihu District, Hangzhou, China
Doi:10.1002/ardp.19632960807
(1963)Doi:10.1016/S0040-4039(00)61861-0
(1985)Doi:10.1021/acs.jmedchem.7b01388
(2018)Doi:10.1016/0008-6215(85)85193-4
(1985)Doi:10.1039/jr9630000240
(1963)Doi:10.1021/je00042a049
(1985)
