Journal of Organic Chemistry p. 3086 - 3091 (1985)
Update date:2022-08-03
Topics:
Schultz, Arthur G.
Lavieri, Frank P.
Snead, Thomas E.
The preparation and intramolecular Diels-Alder reactions of a series of 6-alkenyl-6-(methoxycarbonyl)2,4-cyclohexadien-1-ones are described.The resulting tricyclic β,γ-enones undergo the oxa-di-?-methane rearrangement to give substrates of potential use in the construction of polyquinane natural products.This methodology provides a means for construction of tetracyclic rings of type A by C-alkylation of the synthetic equivalence of enolate B.
View MoreContact:+86-22-83718541
Address:32th Floor, Rongqiao Center Intersection of Changjiang Road and Nankai Six Road Nankai District Tianjin 300102, China
NanJing Rate Biochemicals CO., LTD
Contact:+86-25-84931986
Address:NO. 1 Hongjing Road,Jiangning Science Park,Nanjing,China
Contact:0311-13263231263
Address:jian hua street,Shijiazhuang City, China
Anhui Biochem United Pharmaceutical Co., Ltd.
Contact:0086 551 5167062 / 5228268
Address:No. 30 Hongfeng Road, Hi-Tech Development Zone, Hefei (230088), China
Wuhan Better Organic Technology Inc.
Contact:13307163183
Address:Wuhan Economic&Technology Development Zone, Hubei
Doi:10.1002/ardp.19632960807
(1963)Doi:10.1016/S0040-4039(00)61861-0
(1985)Doi:10.1021/acs.jmedchem.7b01388
(2018)Doi:10.1016/0008-6215(85)85193-4
(1985)Doi:10.1039/jr9630000240
(1963)Doi:10.1021/je00042a049
(1985)
