Intramolecular Catalysis of Oxygen Atom Transfer Reactions of α-Azo Hydroperoxides

DOI: 10.1021/jo00219a053

Source and publish data:

Journal of Organic Chemistry p. 3657 - 3659 (1985)

Update date:2022-07-30

Topics:

Authors:

Baumstark, Alfons L.

Vasquez, Pedro C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00219a053

α-Azo hydroperoxides containing phenolic groups were <*> 10² more reactive at epoxidetions and S-oxidation than electronically similar analugues due to intramolecular acid catalysis of the ionic oxidations.

Full text of DOI:10.1021/jo00219a053

Products guided by the article

Product name:4-Chloro-2-(hydroperoxy-phenylazo-methyl)-phenol

Cas No:97783-05-6

R&D Labs maybe for 97783-05-6

Nanjing Habo Medical Technology Co., Ltd.

Contact:025－85769882

Address:No.108. Ganjiabian east. Qixia District .Nanjing
JinTan Pingsheng Chemical Co.,Ltd

Contact:+86-519-82828200

Address:NO.11Danfengxilu Road,Jintan City,Jiangsu,China
Nanjing Chemlin Chemical Co., Ltd.

website:http://www.echemlin.cn

Contact:+86-25-83697070

Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China
HANGZHOU YUNUO CHEMICAL CO.,LTD

website:http://www.yunuochem.com

Contact:0571-83715115

Address:hangzhou
Radiant Pharma & Tech Company

Contact:+86-511-88790000

Address:338 North Yushan Rd, Zhenjiang, Jiangsu 212016

Relevant to this article

Doi:10.1016/S0022-1139(00)80911-2
(1985)
REACTIONS OF TRIMETHYLSILYL AZIDE WITH ALDEHYDES: FACILE AND CONVENIENT SYNTHESES OF DIAZIDES, TETRAZOLES, AND NITRILES

Doi:10.1016/S0040-4020(01)90003-1
(1987)
Total Synthesis of (-)-Crinine. Use of Tandem Cationic Aza-Cope Rearrangement/Mannich Cyclizations for the Synthesis of Enantiomerically Pure Amaryllidaceae Alkaloids

Doi:10.1002/hlca.19850680324
(1985)
Pyrimidinones. 1. 2-Amino-5-halo-6-aryl-4(3H)-pyrimidinones. Interferon-inducing antiviral agents

Doi:10.1021/jm00150a018
(1985)
Stepwise Reduction of Carbon Dioxide to Formaldehyde and Methanol: Reactions of CO2 and CO2-like Molecules with Hydridochlorobis(cyclopentadienyl)zirconium(IV)

Doi:10.1021/ja00308a019
(1985)
Doi:10.1039/jr9570001172
(1957)

Article Doi