Intramolecular Catalysis of Oxygen Atom Transfer Reactions of α-Azo Hydroperoxides

DOI: 10.1021/jo00219a053

Source and publish data:

Journal of Organic Chemistry p. 3657 - 3659 (1985)

Update date:2022-07-30

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Authors:

Baumstark, Alfons L.

Vasquez, Pedro C.

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Article abstract of DOI:10.1021/jo00219a053

α-Azo hydroperoxides containing phenolic groups were <*> 10² more reactive at epoxidetions and S-oxidation than electronically similar analugues due to intramolecular acid catalysis of the ionic oxidations.

Full text of DOI:10.1021/jo00219a053

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