Desulfurization / α-Alkylation of β-Keto Sulfones

DOI: 10.1021/jo00220a033

Source and publish data:

Journal of Organic Chemistry p. 3846 - 3848 (1985)

Update date:2022-08-05

Topics:

Authors:

Kurth, Mark, J.

O'Brien, Michael, J.

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Article abstract of DOI:10.1021/jo00220a033

A one-pot procedure for the reductive alkylation of β-keto sulfones is described.The method proceeds by a lithium in liquid ammonia desulfurization of the starting β-keto sulfone, resulting in regiospecific generation of an intermediate enolate.Subsequent

Full text of DOI:10.1021/jo00220a033

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