Desulfurization / α-Alkylation of β-Keto Sulfones

DOI: 10.1021/jo00220a033

Source and publish data:

Journal of Organic Chemistry p. 3846 - 3848 (1985)

Update date:2022-08-05

Topics:

Authors:

Kurth, Mark, J.

O'Brien, Michael, J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00220a033

A one-pot procedure for the reductive alkylation of β-keto sulfones is described.The method proceeds by a lithium in liquid ammonia desulfurization of the starting β-keto sulfone, resulting in regiospecific generation of an intermediate enolate.Subsequent

Full text of DOI:10.1021/jo00220a033

Products guided by the article

Product name:Cyclopentanone, 2-(phenylthio)-5-(2-propenyl)-

Cas No:98127-55-0

R&D Labs maybe for 98127-55-0

Shanghai Minstar Chemical Co., Ltd

website:http://www.minstargroup.com

Contact:86-21-18019205509

Address:BUILDING 8, NO.1098, CHUANSHA ROAD, SHANGHAI, CHINA
Chengdu ZY Biochemical Technology Co., LTD

Contact:0086-28-88680086

Address:170 Qingpu Road, Shouan Town, Pujiang County
Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China
Zhejiang Kangfeng Chemical Co.,LTD.

Contact:+86-579-86709687

Address:Xueshizhai Industrial Zone, Weishan Town,Dongyang City, Zhejiang Province ,China
Shenzhen JYMed Technology Co.,Ltd.

website:http://www.jymedtech.com

Contact:+86-755-26612112

Address:1#8,9/F, Biomedicine innovation Industrial Park, No.14, Jinhui Road, Pingshan Sistrict, Shenzhen, China

Relevant to this article

Total synthesis of 5,5′,6,6′-tetrahydroxy-3,3′-biindolyl, the proposed structure of a potent antioxidant found in beetroot (Beta vulgaris)

Doi:10.1016/j.tet.2004.02.043
(2004)
CYANOKETENES. CYCLOADDITIONS OF CHLOROCYANOKETENE TO α,β-UNSATURATED IMINES

Doi:10.1016/S0040-4039(00)88680-3
(1982)
OPHIOXANTHIN, A NEW MARINE CAROTOTENOID SULPHATE FROM THE OPHIUROID OPHIODERMA LONGICAUDUM

Doi:10.1016/S0040-4039(00)94760-9
(1985)
Preparations of Chiral Hydroxyester Synthons via Stereoselective Porcine Pancreatic Lipase-catalysed Hydrolyses of meso-Diesters

Doi:10.1039/c39850001563
(1985)
Arginine-Vasopressin Analogues with High Antidiuretic/Vasopressor Selectivity. Synthesis, Biological Activity, and Receptor Binding Affinity of Arginine-Vasopressin Analogues with Substitutions in Position 1,2,4,7, and 8

Doi:10.1021/jm00151a016
(1986)
Electron Spin Resonance of Re2(μ-H)2(CO)8^+. and Re2(μ-H)2(CO)6(μ-dppm)^-. (dppm = (Ph2P)2CH2). An Indication of Large 5d-6p Mixing in the Odd-Electron Orbital

Doi:10.1021/ja00309a008
(1985)

Article Doi