Acyldemetallation of titanium(III) ?-allylic complexes

DOI: 10.1016/0022-328X(88)87004-9

Source and publish data:

Journal of Organometallic Chemistry p. 23 - 34 (1988)

Update date:2022-08-04

Topics:

Authors:

Kasatkin, A. N.

Kulak, A. N.

Tolstikov, G. A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(88)87004-9

Titanium(III) ?-allylic complexes, prepared by the interaction of 1,3-dienes or trienes with Cp2TiCl2 and n-PrMgBr, react with carboxylic acid chlorides RCOCl (R = alkyl, aryl, alkenyl) to give β, γ-unsaturated ketones in high yields.The reaction takes pl

Full text of DOI:10.1016/0022-328X(88)87004-9

Products guided by the article

Product name:1,6-Heptadien-4-ol, 2,3,4,5,6-pentamethyl-

Cas No:98238-57-4

R&D Labs maybe for 98238-57-4

Henan zhongda Biological Engineering Co., Ltd

Contact:86-28-18109029985

Address:shenzhou road,xuedian industrial estate,zhengzhou city,henan province CHN
Shanghai Taibao Pharmaceutical Technology Co., Ltd(expird)

Contact:021-52217366

Address:shanghai
Huzhou City Linghu Xinwang Chemical Co.,Ltd.

Contact:86-572-3948695/3945236

Address:huzhou
HANGZHOU ICH BIOFARM CO.,LTD

Contact:+86-571-28186845

Address:Room 1224,Eastcom Mansion,398 Wensan Road,Hangzhou,310013 China
Hangzhou GreenCo Science & Technology Co., Ltd.

Contact:86-571-88257303

Address:1713 Room,Jingui Building,Gudun Road,Xihu District,Hangzhou,China

Relevant to this article

Synthesis of saturated benzodioxepinone analogues: Insight into the importance of the aromatic ring binding motif for marine odorants

Doi:10.1002/ejoc.201403142
(2015)
BIS(TRIORGANOMETAL) AND DIORGANOMETAL 1,3-DITHIOLATES (R3M)2(C6H3XS2) AND R2M(C6H3XS2) ( M = Sn, Pb; X = H, Cl)

Doi:10.1016/0022-328X(84)80542-2
(1984)
Biosynthesis of Macrolide Antibiotics. 6. Late Steps in Brefeldin A Biosynthesis

Doi:10.1021/ja00294a045
(1985)
Synthesis of archaeal glycolipid adjuvants-what is the optimum number of sugars?

Doi:10.1016/j.carres.2008.06.021
(2008)
Pestalotiopsin A. Enantioselective construction of potential building blocks derived from antipodal cyclobutanol intermediates

Doi:10.1021/jo070861r
(2007)
Facile synthesis of 1,1,3-tetramethylisoindole N-oxide from 2-chlorobenzoic acid using reverse-cope cyclization as a key step

Doi:10.1055/s-2007-984900
(2007)

Article Doi