Acyldemetallation of titanium(III) ?-allylic complexes

DOI: 10.1016/0022-328X(88)87004-9

Source and publish data:

Journal of Organometallic Chemistry p. 23 - 34 (1988)

Update date:2022-08-04

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Authors:

Kasatkin, A. N.

Kulak, A. N.

Tolstikov, G. A.

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Article abstract of DOI:10.1016/0022-328X(88)87004-9

Titanium(III) ?-allylic complexes, prepared by the interaction of 1,3-dienes or trienes with Cp2TiCl2 and n-PrMgBr, react with carboxylic acid chlorides RCOCl (R = alkyl, aryl, alkenyl) to give β, γ-unsaturated ketones in high yields.The reaction takes pl

Full text of DOI:10.1016/0022-328X(88)87004-9

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