Synthesis of 2'-C-Fluoro-&β-daunomycin. An Example of Configurational Retention in Fluorodehydroxylation with Diethylaminosulfur Trifluoride

DOI: 10.1021/jo00224a052

Source and publish data:

Journal of Organic Chemistry p. 4913 - 4917 (1985)

Update date:2022-09-26

Topics:

Authors:

Castillon, Sergio

Dessinges, Aimee

Faghih, Ramine

Lukacs, Gabor

Olesker, Alain

Thang, Ton That

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00224a052

Fluorodehydroxylation of benzyl 3-azido-3-deoxy-4,6-O-benzylidene-α-D-altropyranoside in the presence of diethylaminosulfur trifluoride proceeded with configurational retention at C-2.On the basis of this reaction a new synthesis of benzyl 3-amino-2,3,6-t

Full text of DOI:10.1021/jo00224a052

Products guided by the article

Product name:benzyl 4-O-benzoyl-2-fluoro-2,3,6-trideoxy-3-(trifluoroacetamido)-β-L-galactopyranoside

Cas No:99018-16-3

R&D Labs maybe for 99018-16-3

Suzhou Wedo Chemicals Co., Ltd.

Contact:86 512 58100425

Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
GLD peptide scientific lnc.

Contact:21-7631221 15884421033

Address:326 Science and technology,Shanghai,China
Zhejiang Genebest Pharmaceutical Co.,Ltd.

Contact:0086-571-63532866

Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China
Shanghai Micro-mega Industry Co., Ltd.

Contact:0086-21-34628682;57153848

Address:Rm413,No.413,West Meilong Road, Minhang District,Shanghai P R China
Improve Medical Technology(Nanxiong) Co., Ltd

Contact:86-751-3836997

Address:No.33, Pingan First Road, Fine Chemical Industry Base, Nanxiong City, Shaoguan, Guangdong, China

Relevant to this article

Decarboxylative Acetoxylation of Aliphatic Carboxylic Acids

Doi:10.1021/acs.joc.9b02092
(2019)
Doi:10.1021/ja01248a041
(1943)
Doi:10.1016/S0031-9422(00)86800-4
(1977)
Diastereoselective addition to an α-alkoxyaldehyde under dipolar (Cram-Felkin) and chelation (Cram-cyclic) controlled conditions: A stereocontrolled synthesis of (+)-blastmycinone

Doi:10.1039/c39850000717
(1985)
Synthesis of Optically Active 2,3-O-Isopropylidene-1-(trimethylsilyl)glyceraldehyde and Other Derivatives of (α-Hydroxyacyl)silane

Doi:10.1021/jo00095a001
(1994)
PHOTOCHEMISTRY OF METAL-METAL BONDED COMPLEXES III. MLCT PHOTOLYSIS OF (CO)5MM'(CO)3(α-diimine) (M, M' = Mn, Re) IN 2-Me-THF AND THF AT 293 K; EVIDENCE OF PHOTOCATALYTIC FORMATION OF ⁺ ^- UPON PHOTOLYSIS IN THE PRESENCE OF P(n-Bu)3

Doi:10.1016/0022-328X(85)88053-0
(1985)

Article Doi