Synthesis of 2'-C-Fluoro-&β-daunomycin. An Example of Configurational Retention in Fluorodehydroxylation with Diethylaminosulfur Trifluoride

DOI: 10.1021/jo00224a052

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Journal of Organic Chemistry p. 4913 - 4917 (1985)

Update date:2022-09-26

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Authors:

Castillon, Sergio

Dessinges, Aimee

Faghih, Ramine

Lukacs, Gabor

Olesker, Alain

Thang, Ton That

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Article abstract of DOI:10.1021/jo00224a052

Fluorodehydroxylation of benzyl 3-azido-3-deoxy-4,6-O-benzylidene-α-D-altropyranoside in the presence of diethylaminosulfur trifluoride proceeded with configurational retention at C-2.On the basis of this reaction a new synthesis of benzyl 3-amino-2,3,6-t

Full text of DOI:10.1021/jo00224a052

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