Journal of the Chemical Society. Chemical communications p. 851 - 853 (1985)
Update date:2022-08-04
Topics:
Cummins, Jane H.
Potter, Barry V. L.
Methylation of 2'-deoxyadenosine 5'-phosphorothioate gives two diastereomeric triesters whose configurations can be assigned by (31)P n.m.r. spectroscopy by methylation of an asymmetric mixture of the diastereoisomers of 2'-deoxyadenosine 5'-O-methylphosphorothioate after configurational assigment; this can be used as a simple method for stereochemical analysis of 2'-deoxyadenosine 5'-<(16)O,(18)O>phosphorothioate.
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