Tetrahedron Letters p. 7183 - 7186 (1997)
Update date:2022-08-03
Topics: Reduction Carbonyl group Organic synthesis Esters Oxidation state Acid chlorides Alkoxy group reactive intermediate Radical intermediate Acyl group Resonance stabilization
Machrouhi, Fouzia
Namy, Jean-Louis
Kagan, Henri B.
Acid chlorides react with esters in the presence of samarium diiodide and catalytic amounts of NiI2 to afford samarium enediolates which can further react with electrophiles such as water or aldehydes to give respectively α-ketols or α-dihydroxyketones.
View MoreSHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD
Contact:+86-755-82412922
Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
Shandong Topscience Biotech Co., Ltd.
Contact:0633-2619278
Address:No. 98 Lanshan West Road, Lanshan District, Rizhao, Shandong Province, P.R. of China
Haitong Chemical Industrial Co.,Ltd.
website:https://www.haitonglongwin.com/
Contact:+86-022-66221018
Address:18-701, No.99, The 4th Street, TEDA,
ZhangJiaGang YaRui Chemical Co.,Ltd.
Contact:0512-58360968
Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Taizhou volsen chemical Co., Ltd
website:http://www.volsenchem.com
Contact:+86-576-88869393
Address:Jiaojiang District, Taizhou, Zhejiang, China.
Doi:10.1021/acs.orglett.8b00337
(2018)Doi:10.1039/c1cc12653a
(2011)Doi:10.1007/s11172-008-0022-y
(2008)Doi:10.1016/j.bmcl.2008.08.009
(2008)Doi:10.1007/BF00955380
(1986)Doi:10.1039/c39860001577
(1986)
