Tetrahedron Letters p. 7183 - 7186 (1997)
Update date:2022-08-03
Topics: Reduction Carbonyl group Organic synthesis Esters Oxidation state Acid chlorides Alkoxy group reactive intermediate Radical intermediate Acyl group Resonance stabilization
Machrouhi, Fouzia
Namy, Jean-Louis
Kagan, Henri B.
Acid chlorides react with esters in the presence of samarium diiodide and catalytic amounts of NiI2 to afford samarium enediolates which can further react with electrophiles such as water or aldehydes to give respectively α-ketols or α-dihydroxyketones.
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Doi:10.1021/acs.orglett.8b00337
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