Stereoselective Oxygenation of 2,3-Diaryloxiranes by Irradiation of Electron Donor-Acceptor Complexes of Tetracyanoethylene

DOI: 10.1039/c39860001577

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Journal of the Chemical Society. Chemical communications p. 1577 - 1579 (1986)

Update date:2022-08-03

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Authors:

Miyashi, Tsutomu

Kamata, Masaki

Mukai, Toshio

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Article abstract of DOI:10.1039/c39860001577

On irradiation of the electron donor-acceptor complexes of 2,3-diaryloxiranes with tetracyanoethylene (TCNE) in the presence of oxygen, cis-trioxolanes are formed stereoselectively; a nonstereoselective <3 + 2>cycloaddition with TCNE competes with trioxol

Full text of DOI:10.1039/c39860001577

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