Tetrahedron p. 2341 - 2346 (1985)
Update date:2022-08-04
Topics:
Marquez, A.
Chuaqui, C. A.
Rodriguez, H.
Zagal, L.
The reaction of Δ2-oxazolin-5-ones 1a and 1b with nickel peroxid in benzene produces the corresponding 4,4-dehydrodimers 5a and 5b as the main products in yields over 75percent.Under the same conditions, the 2-aryl-4-methyl-Δ2-oxazolin-5-ones 1c, 1d and 1e yield five products.In the case of 1c, the constituents of the product mixture were separated and identified as two 4,4-dehydrodimers (meso and dl pair isomers) 5c and 5c', (40.7percent), 2,4-dehydrodimer 6c (34.9percent), acetylanisoylimide 8c(8.5percent) and anisamide (15.9percent).Adequate mechanistic schemes are discussed to account for the products formed.
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Doi:10.1016/S0040-4039(01)02244-4
(2002)Doi:10.1021/ol8004936
(2008)Doi:10.1016/S0040-4020(01)98562-X
(1963)Doi:10.1016/j.bmcl.2007.09.066
(2007)Doi:10.1039/P19850001567
(1985)Doi:10.1134/S1070328407020108
(2007)