Reactions of Aryl Diazonium Salts and Arylazo Alkyl Ethers. 7. Kinetic Studies of the Decomposition of Z Ethers Derived from Some Substituted 2-Nitrobenzene Diazonium Salts

DOI: 10.1021/jo00140a017

Source and publish data:

Journal of Organic Chemistry p. 3673 - 3679 (1982)

Update date:2022-08-11

Topics:

Authors:

Broxton, Trevor J.

McLeish, Michael J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00140a017

Rate constans for the decomposition of (Z)-syn ethers derived from some 4- or 5-substituted 2-nitrobenzenediazonium salts have been measured in both basic ethanol.For some compounds the rate of decomposition is independent of the base concetration while for others the rate is first order in base concetration.Solvent and substituent effects poit to the base-independent mechanism occuring on the free diazonium salt formed by ionization of the Z ether while the base-dependent mechanism occurs on the Z ether itself.Mechanisms are proposed for each of these reactions.

Full text of DOI:10.1021/jo00140a017

Products guided by the article

Product name:4-Chloronitrobenzene

Cas No:100-00-5

R&D Labs maybe for 100-00-5

Zhejiang Sucon Silicone Co.,Ltd

Contact:+86-575-88046692

Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Jiaozuo Zhongwei Special Products Pharmaceutical Co.,Ltd.

website:http://www.zw-pvp.com

Contact:15302105619

Address:Jiaozuo,Henan,China (Mainland)
jintan yufan Medicine Raw materials Co.,Ltd.(expird)

Contact:86-519-82808282

Address:6th,Jincheng Huangzhuang
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Tianjin Jingye Fine Chemicals Co., Ltd.

Contact:+86-15722078107; +86-22-26911407

Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China

Relevant to this article

An immobilized organocatalyst for cyanosilylation and epoxidation

Doi:10.1002/adsc.200606124
(2006)
Ti functionalized hierarchical-pore UiO-66(Zr/Ti) catalyst for the transesterification of phenyl acetate and dimethyl carbonate

Doi:10.1039/c9nj04241e
(2019)
Nickel-catalyzed cross-coupling reaction of aryl fluorides and chlorides with Grignard reagents under nickel/magnesium bimetallic cooperation

Doi:10.1021/ja056327n
(2005)
Synthesis of 5,5-di-(benzotriazol-5-ylmethyl)-2,2-dimethyl-1,3-dioxane-4,6-dione and 5-(benzotriazol-5-ylmethyl)-2,2,5-trimethyl-1,3-dioxane-4.6-dione

Doi:10.1080/00397919308009862
(1993)
Solvent-free synthesis of C₉ and C₁₀ branched alkanes with furfural and 3-pentanone from lignocellulose

Doi:10.1016/j.catcom.2014.11.003
(2015)
One-pot, three-component synthesis of polyfunctionalized benzo[h]pyrazolo[3,4-b][1,6]naphthyridine and benzo[g]pyrazolo[3,4-b]quinoline derivatives in the presence of silver nanoparticles (AgNPs)

Doi:10.1002/jhet.4105
(2020)

Article Doi