Zirconium and hafnium cations rapidly cleave model phosphodiesters in acidic aqueous solutions

DOI: 10.1016/S0040-4039(98)00074-4

Source and publish data:

Tetrahedron Letters p. 1529 - 1532 (1998)

Update date:2022-08-11

Topics:

Authors:

Moss, Robert A.

Zhang, Jing

Ragunathan, Kaliappa G.

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Article abstract of DOI:10.1016/S0040-4039(98)00074-4

Aqueous solutions of 20-fold excess Zr⁴⁺ and Hf⁴⁺ at pH 3.5 (37°C) hydrolyze phosphodiester substrates 1-3 very rapidly. The reactivity of Zr⁴⁺ (with rate constants up to 0.015 s^-1 for 2 at 1 mM Zr⁴⁺)

Full text of DOI:10.1016/S0040-4039(98)00074-4

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Article Doi

Zirconium and hafnium cations rapidly cleave model phosphodiesters in acidic aqueous solutions

DOI: 10.1016/S0040-4039(98)00074-4

Source and publish data:

Authors:

Article abstract of DOI:10.1016/S0040-4039(98)00074-4

Full text of DOI:10.1016/S0040-4039(98)00074-4

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