SELECTIVE OXIDATION OF p-XYLENE
419
reported that is both highly active and selective in oxida- 11. Sabater, M. J., Corma, A., Domenech, A., Forne´s, V., and Garcia, H.,
Chem. Commun. 1285 (1997).
12. Ogunwumi, S. B., and Bein, T., Chem. Commun. 901 (1997).
tion of para-xylene to terephthalic acid.
13. Parton, R. F., Bezoukheanova, C. P., Grobet, J., Grobet, P. J., and
Jacobs, P. A., Stud. Surf. Sci. Catal. 83, 371 (1994).
14. Deshpande, S., Srinivas, D., andRatnasamy, P., J. Catal. 188, 261(1999).
ACKNOWLEDGMENTS
15. Chavan, S., Srinivas, D., and Ratnasamy, P., Top. Catal. 11/12, 359
The authors thank Ms. N. E. Jacob for the help in thermal analysis and
(2000).
Prof. Subhash Padhye and Mr. Nitin Gokhale for electrochemical studies.
16. Chavan, S. A., Halligudi, S. B., Srinivas, D., and Ratnasamy, P., J. Mol.
Catal. 161, 49 (2000).
17. Sumner, C. E., Jr., and Steinmetz, G. R., J. Am. Chem. Soc. 107, 6124
REFERENCES
(1985).
18. Vincent, J. B., Chang, H.-R., Folting, K., Huffman, J. C., Christou, G.,
1. Partenheimer, W., Catal. Today 23, 69 (1995).
2. Sheldon, R. A., and Van Santen, R. A. (Eds.), “Catalytic Oxidation:
Principles and Applications.” World Scientific, Singapore, 1995.
3. Sheldon, R. A., in “The Activation of Dioxygen and Homogeneous
CatalyticOxidation”(D. H. R. Barton, A. E. Martell, andD. T. Sawyer,
Eds.), p. 9. Plenum, New York, 1993.
4. Sheldon, R. A., in “Dioxygen Activation and Homogeneous Catalytic
Oxidation” (L. I. Simandi, Ed.), Vol. 66, p. 573. Elsevier, Amsterdam,
1991.
and Hendrickson, D. N., J. Am. Chem. Soc. 109, 5704 (1987).
19. Balkus, K. J., Jr., and Gabrielov, A. G., J. Inclusion Phenom. Mol.
Recognit. Chem. 21, 159 (1995).
20. Mehrotra, R. C., and Bohra, R., “Metal Carboxylates.” Academic
Press, New York, 1983.
21. Douglas, B. E., McDaniel, D. H., and Alexander, J. J., “Concepts and
Models in Inorganic Chemistry.” Wiley, New York, 1994.
22. Metelski, P. D., Adamian, V. A., and Espenson, J. H., Inorg. Chem. 39,
2434 (2000).
23. Jacob, C. R., Varkey, S. P., and Ratnasamy, P., Appl. Catal. A 182, 91
(1999).
5. Parshall, G. W., and Ittel, S. D., “Homogeneous Catalysis.” Wiley-
Interscience, New York, 1992.
6. Saffer, A., and Barker, R. S., U.S. Patent 2,833,816 (1958).
7. PCT Int. Appl. WO 9,931,038 (24 June 1999).
8. Partenheimer, W., and Schammel, W. P., U.S. Patent 4,786,753
(1988).
9. Broeker, J. L., Partenheimer, W., andRosen, B. I., U.S. Patent5,453,538
(1995).
24. Andersson, K. K., and Gra¨slund, A., Adv. Inorg. Chem. 43, 359 (1995).
25. Siegbahn, P. E. M., and Crabtree, R. H., in “Metal-Oxo and Metal-
Peroxo Species in Catalytic Oxidations in Structure and Bonding”
(B. Meunier, Ed.), Vol. 97, p. 125. Springer-Verlag, Berlin, 2000.
26. Beyer, W. F., and Fridovich, I., Biochemistry 24, 6460 (1985).
27. Law, N. A., Caudu, M. T., and Pecoraro, V. L., Adv. Inorg. Chem. 46,
305 (1999).
10. Hutchings, G. J., Chem. Commun. 301 (1999).