Primary and Secondary Kinetic Deuterium Isotope Effects and Transition-State Structures for Benzylic Chlorination and Bromination of Toluene

DOI: 10.1021/ja00250a028

Source and publish data:

Journal of the American Chemical Society p. 4926 - 4930 (1987)

Update date:2022-08-31

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Authors:

Hanzlik, Robert P.

Schaefer, Angela R.

Moon, Joseph B.

Judson, Charles M.

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Article abstract of DOI:10.1021/ja00250a028

As a chemical model for benzylic hydroxylations effected by cytochrome P-450 enzymes, the chlorination of PhCH3, PhCH2D, PhCHD2, and PhCD3 in a two-phase system of hypochlorite/CH2Cl2 with a phase-transfer catalyst has been investigated.On the basis of th

Full text of DOI:10.1021/ja00250a028

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