Tetrahedron Letters p. 4493 - 4496 (1997)
Update date:2022-08-24
Topics:
King, Malcolm D.
Sue, Rodney E.
White, Rodney H.
Young, David J.
Allylic sulfonyl halides can be generated by halogenolysis of the corresponding triorganotin sulfinates. Allylic sulfonyl bromides and iodides undergo a first order, thermal desulfination with allylic rearrangement to yield the corresponding allylic halides. The desulfination of a cyclic allylic sulfonyl bromide is stereospecific, proceeding with γ-syn bromine migration.
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