Influence of the extent of conversion on enantioselectivity in the nickel-catalyzed cross-coupling reaction

Article abstract of DOI:10.1016/0022-328X(93)83393-A

In the cross coupling reaction between 1-phenylethyl magnesium bromide and vinyl chloride to give 3-phenylbut-1-ene in the presence of nickel(II)bromide complexes of optically active trans-cyclopentane-1,2-diylbis(diarylphosphine) as the catalyst precurso