Journal of the Chemical Society. Chemical communications p. 329 - 330 (1983)
Update date:2022-08-28
Topics:
Tanaka, Ryuichi
Yamabe, Kuniaki
The reaction of chloro(phenyl)ethyne (1) with sodium azide in dimethyl sulphoxide gave the nucleophilic addition product (Z)-α-azido-β-chlorostyrene; phenylethynylnitrene (7) was trapped by the solvent to give N-(phenylethynyl)-S,S-dimethylsulphoximine (4), indicating the prior formation of the hitherto unknown substitution product azido(phenyl)ethyne (6).
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