Tetrahedron Letters p. 4735 - 4738 (1980)
Update date:2022-08-16
Topics:
Guanti, G.
Petrillo, G.
Thea, S.
Cevasco, G.
Stirling, C. J. M.
β-Nitroalcohols 1a-g undergo, in aqueous buffered solution, a specific base catalyzed carbonyl-forming elimination.The transition state for the rate-limiting C-C bond breakage step has been estimated to be rather reactant-like.
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