Tetrahedron p. 7171 - 7176 (1988)
Update date:2022-08-25
Topics:
Mueller, Paul
Gilabert, David Manuel
PhIO, either alone or in conjunction with RuCl2(PPh3)3 is efficient for dehydrogenation of secondary, activated amines to imines.PhIO also effects oxidative decarboxylation of phenylalanine ethyl ester 6a to benzyl cyanide 6d.The mechanistic significance of this latter transformation, which does not occur with other hypervalent iodine oxidants is discussed.
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