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Ruhenium Oxo Complexes of Macrocyclic Tertiary Amines. Synthesis, Electrochemistry and Reactivities of Ruthenium Oxo Complexes of meso-2,3,7,11,12-Pentamethyl-3,7,11,17-tetraazabicycloheptadeca-1(17),13,15-triene (L1), and X-ray Crytal Structure of Trans-ClO4

DOI: 10.1039/DT9890002011

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2011 - 2016 (1989)

Update date:2022-08-11

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Authors:

Che, Chi-MingChe, Chi-Ming

Tang, Wai-TongTang, Wai-Tong

Lee, Wai-OnLee, Wai-On

Wong, Wing-TakWong, Wing-Tak

Lai, Ting-FongLai, Ting-Fong

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Article abstract of DOI:10.1039/DT9890002011

The new complexes trans-Cl, trans-ClO4, and trans-2 (L1=meso-2,3,7,11,12-penamethyl-3,7,11,17-tetraazabicyclo<11.3.1>heptadeca-1(17),13,15-triene)have been reported.Their redox chemistry was studied in comparison with the related Ru-L2-oxo system (L2= 1,4,8,11-tetra-azacyclotetradecane).At pH 1.1, the E0f of the trans-2+/ trns-2+ couple occurs at 0.76 V vs. saturated calomel electrode.The complex cation trans-+ α data> has been determined by X-ray crystallography.The Ru=O distance is 1.777(2) angstroem.The N-Me groups all lie on the same side of the macrocyclic ring.The complex trans-2+ is capable of oxidazing alcohols, styrene, and toluene at room temperature.

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