HYDROLYSIS REACTIONS IN LAMELLAR LIQUID CRYSTALLINE MEDIA ANC OCTANOL/WATER PARTITION COEFFICIENTS.

Article abstract of DOI:10.1080/00268948408072107

Cationic lamellar liquid crystalline morphologies decrease rates of hydrolysis of a series of 4-substituted benzylidene t-butylamine N-oxides as the electron releasing effect increases and they are linear when plotted against sigma ** plus -substituent constants. Rho-values indicate a more sensitive reactivity series in lamellar than in aqueous solvent. Reaction rates in the former solvent parallel the partition coefficients in octanol/water except for the methoxy-derivative.

Full text of DOI:10.1080/00268948408072107

Molecular Crystals and Liquid Crystals
ISSN: 0026-8941 (Print) (Online) Journal homepage: http://www.tandfonline.com/loi/gmcl16
Hydrolysis Reactions in Lamellar Liquid Crystalline
Media and Octanol/Water Partition Coefficients
W. E. Bacon & W. E. Acree Jr.
To cite this article: W. E. Bacon & W. E. Acree Jr. (1984) Hydrolysis Reactions in Lamellar Liquid
Crystalline Media and Octanol/Water Partition Coefficients, Molecular Crystals and Liquid
Crystals, 108:1-2, 177-184, DOI: 10.1080/00268948408072107
To link to this article: http://dx.doi.org/10.1080/00268948408072107
Published online: 20 Apr 2011.
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Date: 20 June 2016, At: 03:22