The Mechanism of Titanium Complex-Catalyzed Reduction of Aryl Halides by Sodium Borohydride Is Strongly Solvent Dependent

DOI: 10.1021/jo00084a003

Source and publish data:

Journal of Organic Chemistry p. 940 - 942 (1994)

Update date:2022-08-11

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Authors:

Liu, Yumin

Schwartz, Jeffrey

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Article abstract of DOI:10.1021/jo00084a003

The titanium complex-catalyzed reduction of aryl halides by sodium borohydride in dimethylacetamide (DMA) or ethers proceeds by electron transfer from a reduced titanium species, yielding an intermediate aryl radical.

Full text of DOI:10.1021/jo00084a003

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