Bulletin of the Chemical Society of Japan p. 1580 - 1582 (1993)
Update date:2022-08-11
Topics:
Ishida, Akito
Uesugi, Tatsumi
Takamuku, Setsuo
Photoirradiation of 2-vinylpyridine in acidic methanol afforded methyl 2-(2-pyridyl)ethylether in a high yield.Reactions in acetic ethanol and 2-propanol also provided the corresponding alkoxyl derivatives along with a considerable amount of 2-ethylpyridine.It was suggested that photoinduced intramolecular charge-shift from the pyridinium ion moiety into the vinyl group initiates the regioselective nucleophilic addition of alcohol.
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