Diastereoselective Addition of Methylcopper- and Dimethylcuprate-Boron Trifluoride Reagents to (S)-(N-Alkylidene)-1-phenylethylamines

DOI: 10.1016/S0957-4166(00)86316-8

Source and publish data:

Tetrahedron Asymmetry p. 291 - 294 (1990)

Update date:2022-08-28

Topics:

Authors:

Boga, Carla

Savoia, Diego

Umani-Ronchi, Achille

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Article abstract of DOI:10.1016/S0957-4166(00)86316-8

The reactions of methylcopper- and dimethylcuprate-boron trifluoride reagents with aldimines derived from (S)-1-phenylethylamine afford with good diastereoselectivity (S,S)-amines from aromatic imines, but the (R,S)-amine from an aliphatic imine

Full text of DOI:10.1016/S0957-4166(00)86316-8

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