Inorganic Chemistry p. 1327 - 1328 (1966)
Update date:2022-08-17
Topics:
Wells, Richard L.
Collins, Alva L.
Two sets of reaction conditions have been found where a dehydrohalogenation reaction occurred when triethylamine-boron trichloride adduct was allowed to react with hexamethyldisilazane. In one case both dehydrohalogenation and cleavage occurred, resulting in the formation of a novel unsymmetrical N-silyl-substituted aminohalogenoborane. Under the other set of conditions an N-silyl-substituted aminodihalogenoborane was produced as a result of only dehydrohalogenation.
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(2017)
