Reactive scattering and electron detachment for collisions of halogen negative ions with HCl, DCl, and HBr

Article abstract of DOI:10.1063/1.454558

Absolute total cross sections have been measured for collisions of Cl-, Br-, and I - with HCl, DCl, and HBr for projectile energies ranging from 5 to 300 eV.The processes investigated include reactive scattering and electron detachment.The reactive scattering cross sections exhibit considerable isotope effects and the collisional dynamics are discussed within the framework of a spectator-stripping model which involves proton or deuteron abstraction.The results for the I- projectile are substantially different from those for Cl- and Br-; this difference is suggested to be related to the relative stability of the molecular anion, HI-.

Full text of DOI:10.1063/1.454558

Reactive scattering and electron detachment for collisions of halogen negative ions
with HCl, DCl, and HBr
R. L. Champion, L. D. Doverspike, M. S. Huq, D. Scott, and Yicheng Wang
Citation: The Journal of Chemical Physics 88, 5475 (1988); doi: 10.1063/1.454558
View online: http://dx.doi.org/10.1063/1.454558
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/88/9?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.0.65.67 On: Fri, 05 Dec 2014 14:06:38
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.0.65.67 On: Fri, 05 Dec 2014 14:06:38
1

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.0.65.67 On: Fri, 05 Dec 2014 14:06:38
1

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.0.65.67 On: Fri, 05 Dec 2014 14:06:38
1

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.0.65.67 On: Fri, 05 Dec 2014 14:06:38
1

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
93.0.65.67 On: Fri, 05 Dec 2014 14:06:38
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