Journal of Physical Chemistry p. 3100 - 3103 (1989)
Update date:2022-08-16
Topics:
Crowley, John N.
Sodeau, John R.
The reactions of hydrocyanic acid with both excited and ground-state oxygen atoms have been examined in low-temperature matrices.The major products of HCN + O(1D2) reaction were isocyanic acid (HNCO) and cyanic acid (HOCN), confirming predictions of the intermediacy of HNCO and oxazirine on the pathway to the final products seen in the gas-phase reaction.In contrast, no evidence was found for reaction between HCN and O(3P) atoms in the matrix.
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