Journal of the Chemical Society - Faraday Transactions p. 2975 - 2978 (1995)
Update date:2022-08-16
Topics:
Ramsay, D. A.
Zhu, Quing-shi
A high-resolution spectrum of the 000-000 band of the <*>A''-<*>A' system of HNO has been recorded in emission from the reaction of the H atoms with NO.No sharp breaking-off in the J structure has been found in the highest sub-band observed.The emission in this sub-band (K'a = 13-K''a = 12) originates in levels above the dissociation limit and arises from a two-body radiative association process.The emission in the other sub-bands originates in levels below the dissociation limit and arises from a three-body recombination process.The mechanism for predissociation is discussed and an interpretation has been given for a hitherto unexplained observation.
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