Journal of the Chemical Society. Perkin transactions II p. 541 - 546 (1987)
Update date:2022-08-31
Topics:
Cipiciani, Antonio
Germani, Raimondo
Savelli, Gianfranco
Bunton, Clifford A.
Mhala, Marutirao
Moffatt, John R.
Reactions of OH- with 2,4-dinitro-1-chloro-benzene and -naphthalene have been examined in solutions of didodecyldimethylammonium chloride and hydroxide.Rate effects were analysed quantitatively in terms of distribution of reactants between water and the colloidal particles.Second-order rate constants at the surface of the particles are very similar to those in normal aqueous micelles of cetyltrimethylammonium hydroxide, chloride, and bromide and p-octyloxybenzyltrimethylammonium bromide and are slightly higher than in water.Similar observations were made on the reaction of OH- with 2,4-dinitro-1-fluorobenzene.
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