
Chemistry Letters p. 1119 - 1122 (1982)
Update date:2022-08-22
Topics:
Kusuda, Kousuke
Hara, Nobuya
West, Robert
Pentachlorotropolone(3) was obtained by treatment of octachlorocycloheptatriene(1) with concentrated sulfuric acid.Chlorination of 3 in liquid chlorine afforded a perchlorinated seven-membered reductone(12).Photolysis of 4-hydroxypentachlorobicyclo<3.2.0>hepta-3,6-dien-2-one(18) gave 3-hydoxypentachlorotropone(19).
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