Journal of Fluorine Chemistry p. 649 - 658 (1982)
Update date:2022-08-30
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Hudlicky, M.
A new synthesis of perfluoro-tert-butyl chloroformate (perfluoro-tert-butoxycarbonyl chloride) is based on the reaction of potassium perfluoro-tert-butoxide with one equivalent of phosgene in xylene or mesitylene.Perfluoro-tert-butyl chloroformate reacts readily with hydroxy, sulfhydryl and amino compounds to give the corresponding perfluoro-tert-butyl alkyl carbonates, thiolcarbonates or carbamates, respectively.Dialkyl carbonates, diaryl carbonates, and symmetrically substituted ureas are formed as by-products and, with some compounds, as exclusive products.Primary amines form isocyanates.
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Doi:10.1002/anie.201209705
(2013)Doi:10.1016/j.jallcom.2004.01.044
(2004)Doi:10.1021/ja00178a020
(1990)Doi:10.1007/s11746-999-0070-y
(1999)Doi:10.1007/s00706-011-0507-5
(2011)Doi:10.1246/cl.1981.1455
(1981)
