Journal of Fluorine Chemistry p. 649 - 658 (1982)
Update date:2022-08-30
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Hudlicky, M.
A new synthesis of perfluoro-tert-butyl chloroformate (perfluoro-tert-butoxycarbonyl chloride) is based on the reaction of potassium perfluoro-tert-butoxide with one equivalent of phosgene in xylene or mesitylene.Perfluoro-tert-butyl chloroformate reacts readily with hydroxy, sulfhydryl and amino compounds to give the corresponding perfluoro-tert-butyl alkyl carbonates, thiolcarbonates or carbamates, respectively.Dialkyl carbonates, diaryl carbonates, and symmetrically substituted ureas are formed as by-products and, with some compounds, as exclusive products.Primary amines form isocyanates.
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(1981)
