Ligand addition to RuCl>4-molecular structure of Ru(C2H4)Cl>2

DOI: 10.1016/0022-328X(91)80265-L

Source and publish data:

Journal of Organometallic Chemistry p. 227 - 235 (1991)

Update date:2022-08-17

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Authors:

Koelle, U.

Kang, Byung-Sun

Englert, U.

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Article abstract of DOI:10.1016/0022-328X(91)80265-L

RuCl>4 (1a) (Cp<*> = η⁵-C5Me4Et) reacts with pyridine or ethylene by trans addition and cleavage to yield the dimers RuL(Cl)>2.The pyridine adduct has been oxidized to the known mixed valence complex <(Cp<*>Ru(py))2(μ-Cl)2>X.

Full text of DOI:10.1016/0022-328X(91)80265-L

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