Photochemical Conversion of Disilanyliron(II) Complexes to Monosilyliron(II) complexes

DOI: 10.1246/cl.1986.1777

Source and publish data:

Chemistry Letters p. 1777 - 1780 (1986)

Update date:2022-08-30

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Authors:

Tobita, Hiromi

Ueno, Keiji

Ogino, Hiroshi

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Article abstract of DOI:10.1246/cl.1986.1777

Photolysis of C6D6 solution of (τ⁵-C5H5)Fe(CO)2SiMe2SiMeR2 (Fp-SiMe2SiMeR2; R = Me, Et) results in the formation of monosilylil-Fp derivatives with the scrambling of alkyl groups.Possible reaction pathways involving silyleneiron intermediates a

Full text of DOI:10.1246/cl.1986.1777

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