Journal of Organometallic Chemistry p. 253 - 260 (1988)
Update date:2022-08-10
Topics:
Lebedev, S. A.
Lopatina, V. S.
Petrov, E. S.
Beletskaya, I. P.
The catalytic system (Ph3P)2NiCl2/zinc/pyridine in acetonitrile is an effective catalyst for reactions of aryl and alkyl bromides with styrene and methyl acrylate.With styrene, the reaction yields vinyl hydrogen replacement (condensation) products, viz. stilbenes and β-alkylstyrenes.Methyl acrylate reacts to give conjugated addition (hydrocondensation) products, methyl esters of β-aryl and β-alkyl propionic acids.
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