Convenient one-pot method for formylation of amines and alcohols using formic acid and 1,1'-oxalyldiimidazole

DOI: 10.1248/cpb.42.1655

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1655 - 1657 (1994)

Update date:2022-08-10

Topics:

Authors:

Kitagawa

Arita Arita

Nagahata

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Article abstract of DOI:10.1248/cpb.42.1655

1,1'-Oxalyldiimidazole (7) reacts with formic acid (8) in acetonitrile at room temperature to give N-formylimidazole (5), which promptly undergoes aminolysis and alcoholysis to yield formamides (2) or formates (4).

Full text of DOI:10.1248/cpb.42.1655

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