Journal of the Chemical Society. Chemical communications p. 294 - 295 (1993)
Update date:2022-08-10
Topics:
Steels, Ivan
Clercq, Pierre J. De
Maskill, Howard
Enforced intramolecular hydrogen bonding in 2-tert-butyl-3-(N,N-dimethylamino)propan-1-ol is shown by the competitive alcoholysis of p-nitrophenyl acetate and 1-acetylimidazole in acetonitrile, and by the corresponding second-order rate constants and activation parameters, to influenece both the rate and the mechanism of catalysed acyl transfer.
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