Direct oxidative deprotection of trimethylsilyl ethers to their corresponding carbonyl compounds with bis (trimethylsilyl) chromate supported onto silica gel in aprotic solvent

Article abstract of DOI:10.1080/00397919908086064

Primary and secondary trimethylsilyl ethers are converted to their carbonyl compounds efficiently using bis (Trimethylsilyl) chromate supported on silica gel in dichloromethane. Benzylic double bonds are not prone to cleavage reactions with this method.

Full text of DOI:10.1080/00397919908086064

This article was downloaded by: [Michigan State University]
On: 28 February 2015, At: 17:28
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
Direct Oxidative Deprotection
of Trimethylsilyl Ethers
to their Corresponding
Carbonyl Compounds with
Bis (trimethylsilyl) Chromate
Supported onto Silica Gel in
Aprotic Solvent
a
a
a
M. M. Heravi , D. Ajami And & K. Tabar-heydar
a
Chemistry & Chemical Engineering Research Center
of Iran , Tehran, Iran , 14335-186
Published online: 17 Sep 2007.
To cite this article: M. M. Heravi , D. Ajami And & K. Tabar-heydar (1999)
Direct Oxidative Deprotection of Trimethylsilyl Ethers to their Corresponding
Carbonyl Compounds with Bis (trimethylsilyl) Chromate Supported onto Silica
Gel in Aprotic Solvent, Synthetic Communications: An International Journal for
Rapid Communication of Synthetic Organic Chemistry, 29:6, 1009-1012, DOI:
10.1080/00397919908086064
To link to this article: http://dx.doi.org/10.1080/00397919908086064
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.

However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions