Journal of Organometallic Chemistry p. 433 - 444 (1989)
Update date:2022-08-29
Topics:
Akermark, Bjoern
Hansson, Sverker
Rein, Tobias
Vagberg, Jan
Heumann, Andreas
Baeckvall, Jan-Erling
In order to investigate the possibility of improving the selectivity in palladium-catalyzed acetoxylation of substituted cycloalkenes and linear alkenes, the influence of added strong acids has been studied.It was found that the product selectivity can be increased in some cases, but also that side reactions lower the total yields when trifluoroacetic or stronger acids are used.The improvement of the selectivity may possibly be due to a change in mechanism for the acetoxylation.
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