Journal of Organic Chemistry p. 4319 - 4320 (1986)
Update date:2022-08-16
Topics:
Nelsen, Stephen F.
Teasley, Mark F.
Treatment of 1-isopropylidene-4,4-dimethyl-2,5-cyclohexadiene (1) with acid in the presence of trifluoroacetic anhydride and trifluoroacetic acid causes efficient formation of the dimer 3,10-bis(1-methylethylidene)-6,6,12,12-tetramethylpentacyclo<6.3.1.02,7.04,11.05,9>dodecane (2), a structural transformation without precedent in the absence of transition metals.
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