Oxidation of Secondary Alcohols over Hydrous Zirconium(IV) Oxide

DOI: 10.1246/bcsj.63.1943

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1943 - 1946 (1990)

Update date:2022-08-12

Topics:

Authors:

Kuno, Hideyuki

Takahashi, Kyoko

Shibagaki, Makoto

Shimazaki, Kazuko

Matsushita, Hajime

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.63.1943

The oxidation of secondary alcohols with ketones was carried out by catalysis with hydrous zirconium(IV) oxide.In the batch reaction system, the oxidation proceeded efficiently to give the corresponding ketones, except for some secondary alcohols.On the other hand, all of the secondary alcohols were efficiently converted to the corresponding ketones in the flow oxidation system.The influence of the hydrogen acceptor on the oxidation rate was investigated by the use of several ketones, and the oxidation rate was influenced by the electron density and steric hindrance around the carbonyl group.The dependence on the reaction temperature was also investigated in the flow reaction system.

Full text of DOI:10.1246/bcsj.63.1943

Products guided by the article

Product name:Menthone

Cas No:10458-14-7

R&D Labs maybe for 10458-14-7

Wuhan Silworld Chemical Co.,Ltd

website:http://www.silworldchemical.com

Contact:+86-27-85613400

Address:No.198 jiangjun Road, Wuhan,China 430033
Zhejiang Kangfeng Chemical Co.,LTD.

Contact:+86-579-86709687

Address:Xueshizhai Industrial Zone, Weishan Town,Dongyang City, Zhejiang Province ,China
Linyi VIHO Chemical Co.,Ltd

Contact:86-15588110016

Address:LINYI CITY,SHANDONG PROVINCE,CHINA
Shochem(Shanghai) Co., Ltd

website:http://www.shochem.com

Contact:021-50800795

Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China
Chengdu Shengnuo Biological Technology Co., Ltd.

Contact:86-028-85275045

Address:Sichuan Province Chengdu hi tech Zone Tianfu Avenue North of 1480

Relevant to this article

Synthesis of functionalised 2,3-dihydroquinolin-4(1: H)-ones vs. quinoline or N -alkenylindole derivatives through sequential reactions of 2-alkynylanilines with ketones

Doi:10.1039/d0ob02106g
(2021)
Electrolytic ZrO₂ coatings. I. Electrochemical aspects

Doi:10.1149/1.2085904
(1991)
Oxidative halogenation of cisplatin and carboplatin: Synthesis, spectroscopy, and crystal and molecular structures of Pt(iv) prodrugs

Doi:10.1039/c4dt02627f
(2014)
A series of water-soluble A-π-A′ typological indolium derivatives with two-photon properties for rapidly detecting HSO₃^-/SO₃^2- in living cells

Doi:10.1039/c7tb00726d
(2017)
Discovery of Bifunctional Oncogenic Target Inhibitors against Allosteric Mitogen-Activated Protein Kinase (MEK1) and Phosphatidylinositol 3-Kinase (PI3K)

Doi:10.1021/acs.jmedchem.5b01655
(2016)
Design, synthesis, and docking studies of quinazoline analogues bearing aryl semicarbazone scaffolds as potent EGFR inhibitors

Doi:10.1016/j.bmc.2017.04.001
(2017)

Article Doi