Heteropolyperoxo- and Isopolyperoxo-tungstates and -molybdates as Catalysts for the Oxidation of Tertiary Amines, Alkenes and Alcohols

DOI: 10.1039/DT9950001833

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1833 - 1838 (1995)

Update date:2022-08-16

Topics:

Authors:

Bailey, Alan J.

Griffith, William P.

Parkin, Bernardeta C.

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Article abstract of DOI:10.1039/DT9950001833

The catalytic oxidation of tertiary amines to the corresponding N-oxides by 4>(3-) (X = P or As, M = Mo or W) and by (2-) with H2O2 as co-oxidant has been studied.Epoxidation of alkenes and oxidation of alcohols by (2-) with H2O2 as co-oxidant has also been examined and compared with that effected by 4>(3-).A possible structure for (2-) is suggested.

Full text of DOI:10.1039/DT9950001833

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