Tetrahedron Asymmetry p. 1607 - 1612 (1993)
Update date:2022-08-11
Topics:
Fantin, Giancarlo
Fogagnolo, Marco
Medici, Alessandro
Pedrini, Paola
Poli, Silvia
Gardini, Fausto
Key Words: Microbial oxidation, Enantioselective resolution, 1-Heteroarylethanol, 1-Arylethanol, 1-(2-Thienyl)cyclopropanemethanol, Bacillus stearothermophilus The enantioselective resolution of the racemic 1-heteroaryl- and 1-arylethanols 1a-h via microbial oxidation with Bacillus stearothermophilus to give the R-enantiomers with high enantiomeric excesses is described.The kinetic resolution of 1-(2-thienyl)ethanol 1b by oxidation with Acinetobacter calcoaceticus anitrat to S-enantiomer (ee 100percent) is also reported.
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