A MODEL FOR METABOLIC ACTIVATION OF DIALKYLNITROSAMINES. OXIDATIVE DEALKYLATION OF N-NITROSO-2-(ALKYLAMINO)ACETONITRILE BY FLAVIN MIMIC IN AQUEOUS SOLUTION

DOI: 10.1016/S0040-4039(00)85149-7

Source and publish data:

Tetrahedron Letters p. 5121 - 5124 (1986)

Update date:2022-08-12

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Authors:

Yano, Yumihiko

Yokoyama, Takeshi

Yoshida, Kitaro

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Article abstract of DOI:10.1016/S0040-4039(00)85149-7

Oxidation-active flavin mimic, benzo<1,2-g, 5,4-g'>dipteridine (BDP), is found to react with N-nitroso-2-(alkylamino)acetonitrile via oxidative dealkylation in aqueous solution.From the kinetic investigations, the oxidation mechanism is proposed.

Full text of DOI:10.1016/S0040-4039(00)85149-7

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