Journal of the Chemical Society. Chemical communications p. 1571 - 1573 (1985)
Update date:2022-08-11
Topics:
Cum, Giampietro
Gallo, Raffaele
Ipsale, Salvatore
Spadaro, Agatino
A heterogenized palladium acetate catalyst, in the presence of oxygen and perchloric acid in ethanol-water caused the direct conversion of terminal and internal monoalkenes into the corresponding alkynes, under mild conditions and in high yields; Wacker-type ketonization occurs with the same reagents in dioxane-water.
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