Selective Synthesis of Alkynes by Catalytic Dehydrogenation of Alkenes over Polymer-supported Palladium Acetate in the Liquid Phase

DOI: 10.1039/c39850001571

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1571 - 1573 (1985)

Update date:2022-08-11

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Authors:

Cum, Giampietro

Gallo, Raffaele

Ipsale, Salvatore

Spadaro, Agatino

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Article abstract of DOI:10.1039/c39850001571

A heterogenized palladium acetate catalyst, in the presence of oxygen and perchloric acid in ethanol-water caused the direct conversion of terminal and internal monoalkenes into the corresponding alkynes, under mild conditions and in high yields; Wacker-type ketonization occurs with the same reagents in dioxane-water.

Full text of DOI:10.1039/c39850001571

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