Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 505 - 516 (1983)
Update date:2022-08-29
Topics:
Anastasi, Christopher
Waddington, David J.
Woolley, Allan
The photo-oxidation of azoethane has been studied by molecular modulation spectroscopy in order to determine the overall rate constant for the second-order removal of ethylperoxy radicals between 303 and 457 K.The principal molecular products of the reaction between 302 and 373 K are acetaldehyde, ethanol and ethyl hydroperoxide.From the reaction rate data and analytical results, the following results have been obtained for the reactions; 2C2H5O2. -> CH3CHO+C2H5OH+O2. (3a); 2C2H5O2. -> 2C2H5O2.+O2. (3b); k3b/k3a increases with temperature from 1.75+/-0.05 at 302 K to 2.45+/-0.15 at 373 K.Arrhenius expressions for reactions (3a) and (3b) have been estimated.
View MoreNEW FORTUNE INDUSTRIAL CO.,LTD.
website:http://newfortune.lookchem.com/
Contact:+86-25-8645-9456
Address:C4-105 GREEN ISLAND FLOWER TOWN
Qingdao Kylin Trading Co., Ltd.
Contact:0086-532-68979884/58972912/68972263/65/88171519
Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
Shanghai Yuanding Chem. Sci. & Tech. Co., Ltd.
website:http://www.shydtec.com
Contact:86-21-57721279
Address:Science and Technology Park, Songjiang District, Shanghai, China
Jinan Jinguilin Chemical Co.,Ltd
Contact:+86-531-81188412
Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan
website:http://www.apeptides.com/en/
Contact:+86-21-60871011
Address:No. 80 Chuanshan Shuyuan Steet,Pudong,Shanghai
Doi:10.1016/j.jcat.2007.02.018
(2007)Doi:10.1002/chem.201403677
(2015)Doi:10.1246/cl.1982.1667
(1982)Doi:10.1021/jm00076a026
(1993)Doi:10.1016/S0040-4039(01)92853-9
(1977)Doi:10.1002/anie.201703334
(2017)
