Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 505 - 516 (1983)
Update date:2022-08-29
Topics:
Anastasi, Christopher
Waddington, David J.
Woolley, Allan
The photo-oxidation of azoethane has been studied by molecular modulation spectroscopy in order to determine the overall rate constant for the second-order removal of ethylperoxy radicals between 303 and 457 K.The principal molecular products of the reaction between 302 and 373 K are acetaldehyde, ethanol and ethyl hydroperoxide.From the reaction rate data and analytical results, the following results have been obtained for the reactions; 2C2H5O2. -> CH3CHO+C2H5OH+O2. (3a); 2C2H5O2. -> 2C2H5O2.+O2. (3b); k3b/k3a increases with temperature from 1.75+/-0.05 at 302 K to 2.45+/-0.15 at 373 K.Arrhenius expressions for reactions (3a) and (3b) have been estimated.
View MoreSHANXI XINTIANYUAN PHARMACEUTICAL CO., LTD.
website:http://www.tychemical.com
Contact:0086-358-3521713 3521715
Address:No. 1 Yintong Road, Shanxi Jiaocheng Economic Development Zone, Xiajiaying Town, Jiaocheng County, Lvliang City, Shanxi Province, China
LIAONING DMSO CHEMICALS CO.,LTD.
website:http://www.chinadmso.com
Contact:+86-427-6503033
Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA
Contact:+49-9398-993127
Address:Untertorstr. 27
website:http://www.weichichem.com
Contact:+8613912949432
Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Contact:+86-10-83993285
Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
Doi:10.1016/j.jcat.2007.02.018
(2007)Doi:10.1002/chem.201403677
(2015)Doi:10.1246/cl.1982.1667
(1982)Doi:10.1021/jm00076a026
(1993)Doi:10.1016/S0040-4039(01)92853-9
(1977)Doi:10.1002/anie.201703334
(2017)
