Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 505 - 516 (1983)
Update date:2022-08-29
Topics:
Anastasi, Christopher
Waddington, David J.
Woolley, Allan
The photo-oxidation of azoethane has been studied by molecular modulation spectroscopy in order to determine the overall rate constant for the second-order removal of ethylperoxy radicals between 303 and 457 K.The principal molecular products of the reaction between 302 and 373 K are acetaldehyde, ethanol and ethyl hydroperoxide.From the reaction rate data and analytical results, the following results have been obtained for the reactions; 2C2H5O2. -> CH3CHO+C2H5OH+O2. (3a); 2C2H5O2. -> 2C2H5O2.+O2. (3b); k3b/k3a increases with temperature from 1.75+/-0.05 at 302 K to 2.45+/-0.15 at 373 K.Arrhenius expressions for reactions (3a) and (3b) have been estimated.
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