ALLYLDIALKYL COMPLEXES OF RUTHENIUM(IV): PREPARATION AND REDUCTIVE C-C BOND FORMATION FOLLOWED BY C-H BOND ACTIVATION

DOI: 10.1016/0022-328X(87)80358-3

Source and publish data:

Journal of Organometallic Chemistry p. C11 - C15 (1987)

Update date:2022-08-30

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Authors:

Nagashima, Hideo

Ara, Ken-Ichi

Yamaguchi, Keitaro

Itoh, Kenji

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Article abstract of DOI:10.1016/0022-328X(87)80358-3

New η³-allyldimethyl complexes Ru(η⁵-C5R5)(η³-C3H5)(CH3)2, where R = H or CH3, are prepared from Ru(η⁵-C5R5)(η³-C3H5)Br2 by alkylation with trimethylaluminium.The Ru(IV) dimethyl complex is thermally

Full text of DOI:10.1016/0022-328X(87)80358-3

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