Tetrahedron Letters p. 5473 - 5476 (1992)
Update date:2022-08-29
Topics:
Barton, Derek H. R.
Beviere, Stephane D.
Chavasiri, Warinthorn
Doller, Dario
Hu, Bin
The Fe(III)-catalyzed ketonization of saturated hydrocarbons by tert-butyl hydroperoxide (TBHP) in pyridine-acetic acid or acetonitrile solution follows the reaction pathway alkane -> alkyl hydroperoxide -> ketone or alcohol.Dioxygen (O2) is the precursor of the oxygen atoms in the alkyl hydroperoxide, the alcohol, and the ketone.
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Doi:10.1021/jo00874a034
(1976)Doi:10.1021/jp001001g
(2000)Doi:10.1021/ja01609a083
(1955)Doi:10.1246/bcsj.9.423
(1934)Doi:10.1016/j.tetlet.2005.04.097
(2005)Doi:10.1021/ja00005a064
(1991)
