GENERATION AND REARRANGEMENT OF A 1-NORBORNENE IN PYROLYSIS OF 1-SILA-OXYNORBORNANES

DOI: 10.1016/S0040-4039(00)96877-1

Source and publish data:

Tetrahedron Letters p. 6421 - 6424 (1987)

Update date:2022-08-12

Topics:

Authors:

Barton, Thomas J.

Yeh Ming-Hsiung

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Article abstract of DOI:10.1016/S0040-4039(00)96877-1

Gas phase pyrolysis of 1-sila-2-oxynorbornenes yields a nortricyclene which is proposed to arise from a β-elimination to form a 1-norbornene, which isomerizes to a 2-norbornacylidene which undergoes γ-CH insertion.

Full text of DOI:10.1016/S0040-4039(00)96877-1

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