Tetrahedron Letters p. 6421 - 6424 (1987)
Update date:2022-08-12
Topics:
Barton, Thomas J.
Yeh Ming-Hsiung
Gas phase pyrolysis of 1-sila-2-oxynorbornenes yields a nortricyclene which is proposed to arise from a β-elimination to form a 1-norbornene, which isomerizes to a 2-norbornacylidene which undergoes γ-CH insertion.
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